Dark souls 3 sacred flame

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The standard Pyromancy Flame will inflict 2.3 times the Attack Rating of the catalyst as critical damage, the Pyromancer's Parting Flame will inflict 2.5 times the Attack Rating of the catalyst for an increase of 9% in damage over the standard Pyromancy Flame (while not inflicting the bonus Combustion damage), and the Demon's Scar will inflict 20% more damage for a 2.76 multiplier. Finally, the flame explodes, knocking the target down and inflicting a critical amount of damage. The flame then burns the target for 9 more instances of damage, each inflicting 0.1 times the Attack Rating of the catalyst as Fire damage. The caster thrusts the flame into the target, inflicting 0.3 times the Attack Rating of the catalyst as Fire damage. If it successfully connects with a valid target, it will place them in a riposte-like state, where the caster is granted invulnerability frames for the duration of the attack animation. The caster conjures a flame in their catalyst hand, then lunges forward in a grabbing motion. The Sacred Flame lies on the left wall among the lava, the other item being an Ember. Make way through the level until reaching the lowermost floor, past the area with several Basilisks and where Knight Slayer Tsorig attacks.

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Found inside a lava pool in the Smouldering Lake.